| 1—酰基—4—氯环己烷与取代芳烃的区域与立体选择性反应 |
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| 引用本文： | 杜卫红,安忠维.1—酰基—4—氯环己烷与取代芳烃的区域与立体选择性反应[J].合成化学,1997,5(2):205-208. |
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| 作者姓名： | 杜卫红 安忠维 |
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| 作者单位： | 西安近代化学研究所 |
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| 摘 要： | 从环己烯合成了１－酰基－４－氯环己烷，发现在其在ＡｌＣｌ３催化与苯，氯苯，溴苯等优先生成反式１－芳基－４－酰基环己烷，与联苯反应时选择性较差。
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| 关 键 词： | 环己烯 酰基 氯环己烷 液晶 环己烷衍生物 |
Regio and Stereoselective Reactin of 1 Acyl 4 chlorocyclohexane with Substituted Aromatics |
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| Du,Wei Hong An,Zhong Wei Xu,Mao Liang Li,Zhi Bin Ma,Dong Hua Wang,Feng Shan Kong,Fan Ling.Regio and Stereoselective Reactin of 1 Acyl 4 chlorocyclohexane with Substituted Aromatics[J].Chinese Journal of Synthetic Chemistry,1997,5(2):205-208. |
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| Authors: | Du Wei Hong An Zhong Wei Xu Mao Liang Li Zhi Bin Ma Dong Hua Wang Feng Shan Kong Fan Ling |
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| Abstract: | Acyl 4 chlorocyclohexane was synthesized by acylation of cyclohexene. GC, GC MS and 1H NMR analyses showed that this compound reacts high regio and stereoselectively with benzene, chlorobenzene and bromobenzene to give trans 1 acyl 4 arylcyclohexanes under the catalysis of AlCl 3. Poor selectivity was observed when it reacts with biphenyl. |
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| Keywords: | Cyclohexene 1 Acyl 4 chlorocyclohexane Alkylation Liquid crystal |
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