| Synthesis and Crystal Structure of N-Phenylbis（ferrocenecarboxyl）imide |
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| 引用本文： | ZHAO Fengb LI Ganga② WU Jing-Xiaa ZHANG Zong-Peia a.Synthesis and Crystal Structure of N-Phenylbis（ferrocenecarboxyl）imide[J].结构化学,2007,26(3):291-294. |
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| 作者姓名： | ZHAO Fengb LI Ganga② WU Jing-Xiaa ZHANG Zong-Peia a |
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| 作者单位： | ZHAO Fengb LI Ganga② WU Jing-Xiaa ZHANG Zong-Peia a (Department of Chemistry，Zhengzhou University，Henan 450052，China) b (Office of Research Administration，Zhengzhou University，Henan 450052，China) |
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| 摘 要： | The ferrocenyl compound,N-phenylbis(ferrocenecarboxyl)imide (C28H23NO2Fe2,Mr=517.17),was synthesized and structurally characterized by means of X-ray single-crystal dif-fraction. It crystallizes in monoclinic,space group C2/c with a=21.374(14),b=10.430(7),c= 10.741(7) ,β=114.184(8)°,V=2184(2) 3,Z=4,Dc=1.573 g/cm3,F(000)=1064,μ(MoKα)= 1.355 mm–1,T=291(2) K,the final R=0.0548 and wR=0.1437 for 1524 observed reflections with I > 2σ(I). In this compound,the nitrogen atom links two ferrocenyl groups and one phenyl group forming a novel imido derivative.
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| 关 键 词： | 二茂铁衍生物 N-苯基双（二茂铁羧酸）酰亚胺 合成 晶体结构 |
Synthesis and Crystal Structure of N-Phenylbis(ferrocenecarboxyl)imide |
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| ZHAO Feng,LI Gang,WU Jing-Xia,ZHANG Zong-Pei.Synthesis and Crystal Structure of N-Phenylbis(ferrocenecarboxyl)imide[J].Chinese Journal of Structural Chemistry,2007,26(3):291-294. |
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| Authors: | ZHAO Feng LI Gang WU Jing-Xia ZHANG Zong-Pei |
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| Institution: | 1. Office of Research Administration, Zhengzhou University, Henan 450052, China
2. Department of Chemistry, Zhengzhou University, Henan 450052, China |
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| Abstract: | The ferrocenyl compound, N-phenylbis(ferrocenecarboxyl)imide (C28H23NO2Fe2, Mr = 517.17), was synthesized and structurally characterized by means of X-ray single-crystal diffraction. It crystallizes in monoclinic, space group C2/c with a = 21.374(14), b = 10.430(7), c =10.741(7)(A), β= 114.184(8)°, V= 2184(2)(A)3, Z = 4, Dc = 1.573 g/cm3, F(000) = 1064,μ(MoKo) =1.355 mm-1, T= 291(2) K, the final R = 0.0548 and wR = 0.1437 for 1524 observed reflections with I ＞ 2σ(I). In this compound, the nitrogen atom links two ferrocenyl groups and one phenyl group forming a novel imido derivative. |
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| Keywords: | N-phenylbis(ferrocenecarboxyl)imide synthesis crystal structure Crystal Structure nitrogen atom links ferrocenyl compound groups forming novel imido derivative final space synthesized characterized means diffraction |
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