Conversion of a (sp3)C-F bond of alkyl fluorides to (sp3)C-X (X = Cl, C, H, O, S, Se, Te, N) bonds using organoaluminium reagents |
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Authors: | Terao Jun Begum Shameem Ara Shinohara Yoshiaki Tomita Masahiro Naitoh Yoshitaka Kambe Nobuaki |
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Institution: | Science and Technology Centre for Atoms, Molecules and Ions Control, Graduate School of Engineering, Osaka University and Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka. terao@chem.eng.osaka-u.ac.jp |
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Abstract: | A simple method for the conversion of (sp(3))C-F bonds of alkyl fluorides to (sp(3))C-X (X = Cl, C, H, O, S, Se, Te, N) bonds has been achieved by the use of a hexane solution of organoaluminum reagents having Al-X bonds. |
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