Facile,Versatile and Stepwise Synthesis of High-Performance Oligomer Acceptors for Stable Organic Solar Cells |
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Authors: | Chen Zhang Jiali Song Jingwei Xue Shijie Wang Zhongwei Ge Yuheng Man Prof Wei Ma Prof Yanming Sun |
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Institution: | 1. School of Chemistry, Beihang University, 100191 Beijing, P. R. China
Contribution: Conceptualization (equal), Data curation (lead), Writing - original draft (lead);2. School of Chemistry, Beihang University, 100191 Beijing, P. R. China
Contribution: Data curation (supporting), Investigation (supporting);3. State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, 710049 Xi'an, P. R. China
Contribution: Data curation (supporting), Investigation (supporting);4. School of Chemistry, Beihang University, 100191 Beijing, P. R. China |
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Abstract: | Oligomer acceptors have recently emerged as promising photovoltaic materials for achieving high power conversion efficiency (PCE) and long-term stability in organic solar cells (OSCs). However, the limited availability of diverse acceptors, resulting from the sole synthetic approach, has hindered their potential for future industrialization. In this study, we present a facile and effective stepwise approach that utilizes two consecutive Stille coupling reactions for the synthesis of oligomer acceptors. To demonstrate the feasibility of the novel approach, we successfully synthesize a trimer acceptor, Tri-Y6-OD, and further systematically investigate the impact of oligomerization on device performance and stability. The results reveal that this approach has significant advantages compared to the conventional method, including reduced formation of unwanted by-products and lower difficulties in purification. Remarkably, the OSC based on PM6 : Tri-Y6-OD achieves an impressive PCE of 18.03 % and maintains 80 % of the initial PCE (T80) for 1523 h under illumination, surpassing the performance of the corresponding small molecule acceptor Y6-OD-based device. Furthermore, the versatility of the synthetic strategy in obtaining diverse acceptors is further demonstrated. Overall, our findings provide a facile, versatile and stepwise way for synthesizing oligomer acceptors, thereby facilitating the development of stable and efficient OSCs. |
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Keywords: | Oligomer Acceptor Solar Cells Stability Synthetic Method |
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