Improved Thermal and Chemical Stability of Oxynitride Phosphor from Facile Chemical Synthesis for Vehicle Cornering Lights |
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Authors: | Dr Dawei Wen Hongmin Liu Zhe Ma Dr Lei Zhou Junhao Li Dr Yue Guo Prof Qingguang Zeng Prof Peter A Tanner Prof Mingmei Wu |
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Institution: | 1. School of Applied Physics and Materials, Wuyi University, Jiangmen, Guangdong, 529020 P. R. China;2. School of Chemical Engineering and Technology, Sun Yat-Sen University, Zhuhai, 519082 P. R. China;3. Guangdong Provincial Key Laboratory of Rare Earth Development and Application, Institute of Resources Utilization and Rare Earth Development, Guangdong Academy of Sciences, Guangzhou, 510651 P. R. China;4. Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong, 999077 P. R. China |
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Abstract: | Orange Eu2+-doped phosphors are essential for light-emitting diodes for cornering lights to prevent fatal road accidents at night, but such phosphors require features of high thermal, chemical stability and facile synthesis. This study reports a series of yellow-orange-red emitting SrAl2Si3ON6:Eu2+ oxynitride phosphors, derived from the SrAlSi4N7 nitride iso-structure by replacing Si4+−N3− with Al3+−O2−. The introduction of a certain amount of oxygen enabled the facile synthesis under atmospheric pressure using the air-stable raw materials SrCO3, Eu2O3, AlN and Si3N4. SrAl2Si3ON6 has a smaller band gap and lower structure rigidity than SrAlSi4N7 (5.19 eV vs 5.50 eV, Debye temperature 719 K vs 760 K), but exhibits higher thermal stability with 100 % of room temperature intensity remaining at 150 °C compared to 85 % for SrAlSi4N7. Electron paramagnetic resonance, thermoluminescence and density functional theory revealed that the oxygen vacancy electron traps compensated the thermal loss. Additionally, no decrease in emission intensity was found after either being heated at 500 °C for 2 hours or being immersed in water for 20 days, implying both of the thermal and chemical stability of SrAl2Si3ON6:Eu2+ phosphors. The strategy of oxynitride-introduction from nitride promotes the development of low-cost thermally and chemically stable luminescent materials. |
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Keywords: | Electron Trap Oxygen Vacancy Oxynitride Phosphor SrAl2Si3ON6 |
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