Highly selective oxidative cleavage of beta-cyclodextrin-epoxide/aziridine complexes with IBX in water |
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| Authors: | Surendra K Krishnaveni N Srilakshmi Reddy M Arjun Nageswar Y V D Rao K Rama |
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| Institution: | Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad-500 007, India. |
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| Abstract: | Water, an environmentally friendly reaction medium, has been utilized for the reaction of IBX with various epoxides 1 and aziridines 2 as their beta-cyclodextrin complexes to afford for the first time alpha-hydroxyketones 3 and alpha-aminoketones 4, respectively. |
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