| THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORIDE |
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| 作者姓名： | 张廷理 胡荣祖 张明南 王亚平 梁燕军 汪渊 |
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| 作者单位： | Xian Modern Chemistry Research Institute，Xian Modern Chemistry Research Institute，Xian Modern Chemistry Research Institute，Xian Modern Chemistry Research Institute，Xian Modern Chemistry Research Institute，Xian 710061，Xian Modern Chemistry Research Institute，Xian 710061 Xian 710061，Xian 710061，Xian 710061，Xian 710061 |
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| 摘 要： | The polymerization thermokinetics of pyrrole in the presence of iron trichloride art studied by using a Calvet microcalorimoter. The apparent activation energy, the pre-exponential constant and reaction order of this reaction in the temperature range of 25.2—37℃are 34.5 KJ·mol~(-1), 10~(2.74)S~(-1) and 1 respectively. The activation free-energies of this reaction at 25.2°, 30°and 37℃are 91.8, 92.9 and 94.2 KJ·mol~(-1) respectively.
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| 收稿时间： | 1989-07-05 |
THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORID E |
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| ZHANG Tingli,HU Rongzu,ZHANG Mingnan,WANG Yaping,LIANG Yanjun,WANG Yuan.THE POLYMERIZATION THERMOKINETICS OF PYRROLE IN THE PRESENCE OF IRON TRICHLORIDE[J].Chinese Journal of Polymer Science,1991,0(1):19-23. |
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| Authors: | ZHANG Tingli HU Rongzu ZHANG Mingnan WANG Yaping LIANG Yanjun WANG Yuan |
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| Institution: | Xian Modern Chemistry Research Institute; Xian; Xian 710061 Xian |
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| Abstract: | The polymerization thermokinetics of pyrrole in the presence of iron trichloride art studied by using a Calvet microcalorimoter. The apparent activation energy, the pre-exponential constant and reaction order of this reaction in the temperature range of 25.2—37℃ are 34.5 KJ·mol-1, 10-1S2.74 and 1 respectively. The activation free-energies of this reaction at 25.2°, 30°and 37℃ are 91.8, 92.9 and 94.2 KJ·mol-1 respectively. |
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| Keywords: | Thermokinetics Pyrrole Polypyrrole Polymerization |
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