Crystal structure of a complex of nickel(II) with 2-amino-4-imino-2-pentene |
| |
Authors: | S I Dorovskikh K V Zherikova N V Kuratieva N B Morozova |
| |
Institution: | 1.A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division,Russian Academy of Sciences,Novosibirsk,Russia |
| |
Abstract: | The structure of a nickel(II) complex with 2-amino-4-iminopentane is determined by X-ray crystallography at 150 K. Crystal data for C10H18N4Ni are: a = 10.9802(3)Å, b = 13.5780(4)Å, c = 8.0935(2)Å, β = 107.304(1)°, space group P21/c, V = 1152.04(5) Å3, Z = 4, d x = 1.459 g/cm3, R = 0.0283. The structure is molecular; the metal atom is coordinated by four nitrogen atoms of two β-diimine ligands. The Ni-N distances in Ni(NacNac)2 fall within 1.8571–1.8623 Å. The molecules in the crystal are joined by only van der Waals interactions. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|