Second-order quadrupole splittings of the95Mo NMR signal in Mo(CO)6 and their reduction by sample spinning

The lifetimes of higher lying¹S_0?,¹D_2?, and¹F ₃ ⁰ -levels and of the 5s 7s³S₁- and 5p^{2 3}P₁-state in the Sr I-spectrum have been measured by a time resolved registration of the fluorescent intensity. The¹S_0? and¹D₂-levels were populated selectively by a two step optical excitation using two pulsed dye lasers. In the case of the¹F ₃ ⁰ -levels and of the³S_1?,³P₁-states the first excitation step was performed by a discharge, for the second, selective step a pulsed dye laser was used. The agreement of the experimental results with theoretically obtained lifetimes is satisfactory only in some cases.