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Disconnections in simple and complex structures
Authors:R C Pond  X Ma  J P Hirth  T E Mitchell
Institution:1. Department of Engineering , University of Liverpool , Brownlow Hill, Liverpool L69 3BX, UK r.c.pond@liverpool.ac.uk;3. Department of Engineering , University of Liverpool , Brownlow Hill, Liverpool L69 3BX, UK;4. 114 E. Ramsey Canyon Rd. , Hereford, AZ, 85615, USA;5. Structure–Property Relations Group, MST-8, Mail Stop G755, Los Alamos National Laboratory , Los Alamos, NM, 87545, USA
Abstract:Disconnections are interfacial defects with dislocation and step character; for example, twinning dislocations in homo-phase and transformation dislocations in hetero-phase materials. They play important structural roles and are classified as either ‘perfect’, separating energetically degenerate regions of interface, or ‘partial’, bounding a faulted region. In kinetic mechanisms, disconnection motion can be glissile, by conservative climb or climb. In the present paper, disconnection mobility is analyzed in terms of shear and shuffle-type atomic displacements and diffusional flux. This is applied to a sequence of hetero-phase materials with increasing structural complexity, namely the β to α transformation in Ti, θ′ precipitation in Al(Cu) and the orthorhombic to monoclinic martensitic transformation in ZrO2. A disconnection source mechanism in Ti, involving conservative climb, is also described.
Keywords:
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