Derivatives of exo-5-Aminomethyl-endo-5-methylbicyclo[2.2.1]hept-2-ene and exo-5-Aminomethyl-endo-5-methyl-exo-2,3-epoxybicyclo[2.2.1]heptane |
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| Authors: | A. O. Kas'yan E. T. Zlenko S. I. Okovityi E. A. Golodaeva L. I. Kas'yan |
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| Affiliation: | (1) Dnepropetrovsk National University, Nauchnyi per. 13, Dnepropetrovsk, 49625, Ukraine;(2) Dnepropetrovsk State Medical Academy, Dnepropetrovsk, Ukraine |
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| Abstract: | exo-5-Aminomethyl-endo-5-methylbicyclo[2.2.1]hept-2-ene and its 2,3-epoxy derivative were synthesized, and their geometric parameters and conformational properties, in particular the barriers to rotation of the aminomethyl fragment about the exocyclic C5ÄC bond, were studied by the molecular-mechanics method (MMX) and compared with those found for structurally related exo-5-aminomethylbicyclo[2.2.1]hept-2-ene. The title compounds were brought into reactions with electrophilic reagents: arenesulfonyl chlorides, isocyanates, and isothiocyanates. |
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