Catalytic enantioselective 1,2-diboration of 1,3-dienes: versatile reagents for stereoselective allylation |
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| Authors: | Kliman Laura T Mlynarski Scott N Ferris Grace E Morken James P |
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| Institution: | Department of Chemistry, Boston College, Chestnut Hill, MA 02467, USA. |
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| Abstract: | More with boron: The development of catalytic enantioselective 1,2-diboration of 1,3-dienes enables a new strategy for enantioselective carbonyl allylation reactions (see scheme). These reactions occur with outstanding levels of stereoselection and can be applied to both monosubstituted and 1,1-disubstituted dienes. The carbonyl allylation reactions provide enantiomerically enriched functionalized homoallylic alcohol products. |
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| Keywords: | allylation asymmetric catalysis boron enantioselectivity synthetic methods |
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