New class of chiral ligands derived from isosorbide: first application in asymmetric transfer hydrogenation |
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| Authors: | Khanh-Duy Huynh Houssein Ibrahim Martial Toffano Giang Vo-Thanh |
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| Affiliation: | Institut de Chimie Moléculaire et des Matériaux d’Orsay (ICMMO—UMR 8182), Laboratoire de Catalyse Moléculaire, Université Paris-Sud 11, 91405 Orsay, Cedex, France |
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| Abstract: | A new class of β-amino alcohol and diamine ligands was prepared from isosorbide as a chiral renewable resource. The original wedge-shaped structure of isosorbide offers an interesting chiral pocket to promote the metal-catalyzed enantioselective reduction of ketones by transfer hydrogenation. |
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