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| 一种新的配位聚合物[Cd(SCN)2(POM)2]n的合成和晶体结构(英) | |
| 引用本文： | 冯小军,杨家祥,于文涛,Fun Hoong-Kun,吴杰颖,田玉鹏.一种新的配位聚合物[Cd(SCN)2(POM)2]n的合成和晶体结构(英)[J].无机化学学报,2004,20(4):403-406. |
| 作者姓名： | 冯小军 杨家祥 于文涛 Fun Hoong-Kun 吴杰颖 田玉鹏 |
| 作者单位： | 1. 安徽大学化学化工学院,合肥,230039 2. 山东大学晶体所国家重点实验室,济南,250100 3. X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia |
| 基金项目： | 国家自然科学基金，国家重点项目，安徽省自然科学基金，马来西亚科技大学校科研和教改项目 |
| 摘 要： | The one-dimensional chain self-assembled coordination polymer, Cd(SCN)2(POM)2]n(where POM is 3-methyl-4-nitropyridine-N-oxide), was synthesized and characterized. The crystal data for the title coordination polymer: monoclinic, space group P21/c, a = 1.182 3(1) nm, b = 0.591 1(1) nm, c = 1.419 2(1) nm, β = 102.875(1)°, Z=2, μ = 1.391 mm-1, final R1 = 0.062 8, wR2 = 0.145 2. The coordination polymer exhibits a strong fluorescent emission band at ca. 518 nm. CCDC: 211506. |
| 关 键 词： | 自组装 配位聚合物 固体荧光 热重分析 |
Synthesis and Crystal Structure of a Novel Coordination Polymer of [Cd(SCN)2(POM)2]n |
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| FENG Xiao-Jun,YANG Jia-Xiang,YU Wen-Tao,FUN Hoong-Kun,WU Jie-Ying and TIAN Yu-Peng.Synthesis and Crystal Structure of a Novel Coordination Polymer of [Cd(SCN)2(POM)2]n[J].Chinese Journal of Inorganic Chemistry,2004,20(4):403-406. | |
| Authors: | FENG Xiao-Jun YANG Jia-Xiang YU Wen-Tao FUN Hoong-Kun WU Jie-Ying and TIAN Yu-Peng |
| Institution: | Department of Chemistry, Anhui University, Hefei 230039,State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100,State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100,X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia,Department of Chemistry, Anhui University, Hefei 230039 and Department of Chemistry, Anhui University, Hefei 230039 |
| Abstract: | The one-dimensional chain self-assembled coordination polymer, Cd(SCN)2(POM)2]n (where POM is 3-methyl4-nitropyridine-N-oxide), was synthesized and characterized. The crystal data for the title coordination polymer:monoclinic, space group P21/c, a = 1.182 3(1) nm, b = 0.591 1(1) nm, c = 1.419 2(1) nm, β = 102.875(1)o, Z=2,μ = 1.391 mm-1, final R1 = 0.062 8, wR2 = 0.145 2. The coordination polymer exhibits a strong fluorescent emission band at ca. 518 nm. CCDC: 211506. |
| Keywords: | self-assembled coordination polymer solid state fluorescence POM |
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