Mechanism of homogeneous catalysis of isotope exchange during interaction of dihydrogen with alkaline solutions |
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| Authors: | A A Medvinskii Yu M Baikov N N Bulgakov G G Saveliev and E K Shalkova |
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| Institution: | (1) Polytechnical Institute, Tomsk, USSR;(2) Institute of Catalysis, Novosibirsk, USSR;(3) Physico-Technical Institute, Leningrad, USSR |
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| Abstract: | The mechanism of hydrogen isotope exchange in aqueous alkaline solutions (AAS) of D2 has been studied using Interacting Bonds Method (IBM) data obtained for hydrogen interaction with the molecular ion H3O
2
–
. Models for the activated and metastable intermediate complexes are described.
              -    D2    (  ).           (  )  H3O
2
–
. .
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| Keywords: | |
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