| KINETICS OF POLYMERIZATION OF METHYL METHACRYLATE INITIATED BY COPPER POLYPROPYLENE—BASED POLY（OXIME—IMIDODIACETATE）—SODIUM SULFITE SYSTEM |
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| 作者姓名： | WUJinyuan YANGChaoxiong 等 |
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| 摘 要： | ![]()
The aqueous polymerization of methyl methacrylate intiated by copper polypropylene-based poly(oxime-imidodiacetate)(P-Cu)-sodium sulfite system has been investigated.The overall rate of polymerization(Rp) was found to be Rp=5.8×10^12e^-84.1KJ/RT[MMA]^1.4[P-Cu]^0[Na2SO3]^0.50 A mechanism of “coordination-proton transfer”for the production of initiating species was proposed and discussed.
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| 关 键 词： | 动力学 聚合反应 聚丙烯铜 甲基丙烯酸甲酯 聚（肟－亚氨双乙酸）－亚硫酸钠 |
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