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Single-walled Carbon Nanotubes as Electrode Materials for Supercapacitors
引用本文:徐斌 吴锋 王芳 陈实 曹高萍 杨裕生. Single-walled Carbon Nanotubes as Electrode Materials for Supercapacitors[J]. 中国化学, 2006, 24(11): 1505-1508. DOI: 10.1002/cjoc.200690284
作者姓名:徐斌 吴锋 王芳 陈实 曹高萍 杨裕生
作者单位:[1]School of Chemical Engineering & Environment, Beijing Institute of Technology, Beijing 100081, China [2]Research Institute of Chemical Defense, Beijing 100083, China [3]Department of Chemistry, Tsinghua University, Beijing 100084, China
基金项目:Project supported by the National Key Basic Research and Development 973 Program (No.2002CB211800) and the National Key Program for Basic Research of China (No.2001CCA05000).Acknowledgement The authors thank Prof. Y. S. Huang and Dr. Y. Huang, Nankai University for providing the SWNT sample.
摘    要:Large-scale synthesized single-walled carbon nanotubes (SWNT) prepared by electric arc discharge method and a mixture of NiO and Y2O3 as catalyst have been used as electrode materials for supercapacitors. N2 adsorption/desorption measurement shows that the SWNT is a microporous and mesoporous material with specific surface area 435 m^2·g^-1. The specific capacitance of the nitric acid treated SWNT in aqueous electrolyte reaches as high as 105 F/g, which is a combination of electric double layer capacitance and pseudocapacitance. The SWNT-based capacitors also have good charge/discharge reversibility and cycling perdurability.

关 键 词:单壁碳纳米管 超电容器 电极材料 电荷转移
收稿时间:2006-03-11
修稿时间:2006-03-112006-03-23

Single-walled Carbon Nanotubes as Electrode Materials for Supercapacitors
XU, Bin, WU, Feng, WANG, Fang, CHEN, Shi, CAO, Gao-Ping, YANG, Yu-Sheng. Single-walled Carbon Nanotubes as Electrode Materials for Supercapacitors[J]. Chinese Journal of Chemistry, 2006, 24(11): 1505-1508. DOI: 10.1002/cjoc.200690284
Authors:XU   Bin   WU   Feng   WANG   Fang   CHEN   Shi   CAO   Gao-Ping   YANG   Yu-Sheng
Abstract:Large‐scale synthesized single‐walled carbon nanotubes (SWNT) prepared by electric arc discharge method and a mixture of NiO and Y2O3 as catalyst have been used as electrode materials for supercapacitors. N2 adsorption/desorption measurement shows that the SWNT is a microporous and mesoporous material with specific surface area 435 m2·g?1. The specific capacitance of the nitric acid treated SWNT in aqueous electrolyte reaches as high as 105 F/g, which is a combination of electric double layer capacitance and pseudocapacitance. The SWNT‐based capacitors also have good charge/discharge reversibility and cycling perdurability.
Keywords:single-walled carbon nanotube   supercapacitor   capacitance
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