Geometric effects on surface roughness in electrodeposition |
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Authors: | BuAli, Q. Johns, L. E. Narayanan, R. |
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Affiliation: | Department of Chemical Engineering, University of Florida, Gainesville, FL 32611, USA |
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Abstract: | ** Email: ranga{at}ufl.edu Our aim is to understand the early stages of roughness growthin electrodeposition. We present a study of the branching ofsteady planar electrode surfaces to steady non-planar electrodesurfaces as the voltage imposed at a cathode is decreased throughits critical value. We aim to discover the type of branchingand to learn whether or not the new branches can be detectedby measuring the current. The cross-sectional shape of the electrodemakes a difference. Circular electrodes lead to transcriticalbranching; ordinarily, rectangular electrodes lead to a pitchfork,sometimes forward and sometimes backward. |
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Keywords: | electrodeposition surface roughness stability branching non-linear. |
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