A nonsymmetric pincer-catalyzed Suzuki-Miyaura arylation of benzyl halides and other nonactivated unusual coupling partners |
| |
| Authors: | Inés Blanca Moreno Isabel SanMartin Raul Domínguez Esther |
| |
| Affiliation: | Kimika Organikoa II Saila, Zientzia eta Teknologia Fakultatea, Euskal Herriko Unibertsitatea, 644 P.K., 48080 Bilbao, Spain. |
| |
| Abstract: | ![]()
The catalytic activity of a PCN-type palladium pincer complex is evaluated in the construction of C(sp(2))-C(sp(2)) and C(sp(2))-C(sp(3)) bonds by Suzuki-Miyaura cross-couplings employing nontypical substrates such as benzyl halides, alpha-haloenones, or alkylboronic acids as coupling partners. Most of the reported reactions are achieved in aqueous media, with all of the advantages implied. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
