An approach to the imine ring system of pinnatoxins |
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Authors: | Pelc Matthew J Zakarian Armen |
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Affiliation: | Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, USA. |
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Abstract: | ![]() [reaction: see text] A concise stereoselective approach to the spirobicyclic imine fragment of pinnatoxins and pteriatoxins is described. The approach relies on a tandem reaction sequence involving consecutive sigmatropic rearrangements to build the quaternary chiral center at the core of the spirobicyclic ring system. |
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