| 鲁米诺偶联酞菁的合成及其光谱性质的研究 |
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| 引用本文： | 黄新,李忠玉,宾月景,黄蕾,张复实.鲁米诺偶联酞菁的合成及其光谱性质的研究[J].影像科学与光化学,2007,25(3):209-213. |
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| 作者姓名： | 黄新 李忠玉 宾月景 黄蕾 张复实 |
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| 作者单位： | 1. 清华大学, 化学系, 有机光电子与分子工程教育部重点实验室, 北京, 100084;2. 清华大学, 化学系, 有机光电子与分子工程教育部重点实验室, 北京, 100084;吉林化工学院, 化学工程系, 吉林, 132022 |
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| 基金项目： | 国家自然科学基金
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国家重点基础研究发展计划(973计划) |
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| 摘 要： | 本文通过重氮化反应设计、合成了鲁米诺偶联的氨基锌酞菁,对其电子吸收光谱和荧光光谱性质进行了研究,结果表明该分子激发单重态可能以振动驰豫的方式使大部分能量耗散,鲁米诺偶联前后,氨基取代锌酞菁的荧光光谱有明显差别,为进一步开发酞菁类荧光光存储材料提供了理论依据.
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| 关 键 词： | 鲁米诺 氨基取代锌酞菁 电子转移 荧光存储 |
| 收稿时间： | 2006-10-13 |
Study on Synthesis and Spectral Properties of Phthalocyanine Conjugating Luminols |
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| HUANG Xin,LI Zhong-yu,BIN Yue-jing,HUANG Lei,ZHANG Fu-shi.Study on Synthesis and Spectral Properties of Phthalocyanine Conjugating Luminols[J].Imaging Science and Photochemistry,2007,25(3):209-213. |
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| Authors: | HUANG Xin LI Zhong-yu BIN Yue-jing HUANG Lei ZHANG Fu-shi |
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| Institution: | 1. Key Laboratory of Organic Optoelectronics and Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;2. Department of Chemical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, P. R. China |
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| Abstract: | α-Tetra-amino-phthalocyanine zinc(Ⅱ) conjugating luminols was designed and synthesized by diazotization method.The electronic absorption spectra and fluorescence spectra of the compound in DMF have been measured and studied.The phenomena of intramolecular electron transfer are found and the fluorescence of phthalocyanine was quenched significantly by luminol moiety.These results showed potential applications in fluorescence data storage. |
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| Keywords: | luminol amino substituted phthalocyanine zinc(Ⅱ) electron transfer fluorescence data storage |
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