| Hydrothermal Synthesis and Crystal Structure of a New Zero-dimensional Complex: [Zn(H_2BPTC)(phen)_2]_n·3nH_2O |
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| 引用本文： | 李秀梅,董艳辉,王庆伟,崔运成,刘博.Hydrothermal Synthesis and Crystal Structure of a New Zero-dimensional Complex: [Zn(H_2BPTC)(phen)_2]_n·3nH_2O[J].结构化学,2007,26(12):1495-1498. |
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| 作者姓名： | 李秀梅 董艳辉 王庆伟 崔运成 刘博 |
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| 作者单位： | Department of Chemistry Tonghua Teachers College，Department of Pharmacy and Food Science Tonghua Teachers College，College of Chemistry Jilin Normal University，College of Chemistry Jilin Normal University，College of Chemistry Jilin Normal University，Tonghua 134002 China，Tonghua 134002 China，Siping 136000 China，Siping 136000 China，Siping 136000 China |
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| 基金项目： | The project was supported by the Education Office of Jilin Province (No. 0047) |
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| 摘 要： | A new metal-organic coordination complex Zn(H2BPTC)(phen)2]n·3nH2O (BPTC = 3,3′,4,4′-benzophenone tetracarboxylate, phen = 1,10-phenanthroline) 1 has been obtained from hydrothermal reaction and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. In compound 1, the zinc cation is hexa-coordinated with two carboxylate oxygen atoms from one H2BPTC ligand and four nitrogen atoms from two different phen ligands, showing a slightly distorted octahedral geometry. Crystal data: C41H30N4O12Zn, Mr = 836.06, monoclinic, P21/c, a = 14.2714(9), b = 16.9386(10), c = 15.0151(9) , β = 101.3420(10)o, V = 3558.8(4) 3, Dc = 1.560 g/cm3, μ(MoKα) = 0.766 mm-1, F(000) = 1720, Z = 4, R = 0.0439 and wR = 0.1157 for 4123 observed reflections with I > 2σ(I).
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| 关 键 词： | 3 3′ 4 4′-benzophenone tetracarboxylate crystal structure zinc(II) complex |
Hydrothermal Synthesis and Crystal Structure of a New Zero-dimensional Complex: [Zn(H_2BPTC)(phen)_2]_n·3nH_2O |
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| LI Xiu-Mei,DONG Yan-Hui,WANG Qing-Wei,CUI Yun-Cheng,LIU Bo,.Hydrothermal Synthesis and Crystal Structure of a New Zero-dimensional Complex: [Zn(H_2BPTC)(phen)_2]_n·3nH_2O[J].Chinese Journal of Structural Chemistry,2007,26(12):1495-1498. |
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| Authors: | LI Xiu-Mei DONG Yan-Hui WANG Qing-Wei CUI Yun-Cheng LIU Bo |
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| Abstract: | A new metal-organic coordination complex Zn(H2BPTC)(phen)2]n·3nH2O (BPTC = 3,3′,4,4′-benzophenone tetracarboxylate, phen = 1,10-phenanthroline) 1 has been obtained from hydrothermal reaction and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. In compound 1, the zinc cation is hexa-coordinated with two carboxylate oxygen atoms from one H2BPTC ligand and four nitrogen atoms from two different phen ligands, showing a slightly distorted octahedral geometry. Crystal data: C41H30N4O12Zn, Mr = 836.06, monoclinic, P21/c, a = 14.2714(9), b = 16.9386(10), c = 15.0151(9) , β = 101.3420(10)o, V = 3558.8(4) 3, Dc = 1.560 g/cm3, μ(MoKα) = 0.766 mm-1, F(000) = 1720, Z = 4, R = 0.0439 and wR = 0.1157 for 4123 observed reflections with I > 2σ(I). |
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| Keywords: | 3 3′ 4 4′-benzophenone tetracarboxylate crystal structure zinc(II) complex |
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