(6-4)-photolyase activity requires a charge shift reaction |
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| Authors: | Stafforst Thorsten Diederichsen Ulf |
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| Affiliation: | Institut für Organische und Biomolekulare Chemie, Georg-August-Universit?t G?ttingen, Tammannstrasse 2, D-37077 G?ttingen, Germany. |
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| Abstract: | A model compound containing a thymine oxetane moiety linked to a flavin chromophore was investigated regarding (6-4)-photolyase activity. The need for a charge shift reaction was demonstrated by a detailed pH-dependent kinetic analysis. |
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