Two-photon spectroscopy of core excitons in barium fluoride using synchrotron radiation and laser light

We have conducted two-photon spectroscopy of core excitons in BaF(2). Synchrotron radiation and laser light were used for 5p core-electron excitation and Auger-free luminescence was detected as the signal. Two-photon excitation enables access to f and p orbitals that cannot be reached by one-photon excitation of electrons in p orbitals. It has been found that the spin-orbit splittings of 4f and 6p states of the Ba ion in BaF(2) are 0.7 +/- 0.1 and 1.4 +/- 0.1 eV, respectively.