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Kinetic analysis of n-butane hydrogenolysis on a Ru/Al2O3catalyst |
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| Authors: | Geoffrey C Bond Geoffrey C Bond Andrew D Hooper and Andrew D Hooper |
| Institution: | (1) Brunel University, Uxbridge, UB8 3PH, U.K.;(2) Brunel University, Uxbridge, UB8 3PH, U.K.;(3) Brunel University, Uxbridge, UB8 3PH, U.K.;(4) Brunel University, Uxbridge, UB8 3PH, U.K. |
| Abstract: | Summary Analysis of the kinetics of the hydrogenolysis of n-butane on a Ru/Al2O3catalyst permits recognition of the range of H2:n-butane ratio where carbon formation can be neglected. Variation of the apparent activation energy with H2pressure results from a variable contribution of its heat of adsorption to the true activation energy. Effects on product selectivities and on response of rate to H2pressure due to oxidation and low-temperature reduction are also traced to differences in heats of adsorption.</o:p> |
| Keywords: | ruthenium n-butane Hydrogenolysis |
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