Addition reactions of ethoxycarbonylnitrene and ethoxycarbonylnitrenium ion to allylic ethers |
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| Authors: | M.Antonietta Loreto Lucio Pellacani Paolo A Tardella Elena Toniato |
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| Affiliation: | Dipartimento di Chimica, Università “La Sapienza”, I-00185 Roma, Italy |
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| Abstract: | ![]()
Ethoxycarbonylnitrene (EtOCON) generated by α-elimination adds cleanly to allylic ethers giving substituted aziridines. Similar addition via nitrenium ion (EtOCONH+) gives derivatives of β-amino alcohols. |
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