Synthesis of esters by rhodium(i) catalyzed borate ester-benzylic bromide carbonylation reactions |
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| Authors: | James B. Woell Howard Alper |
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| Affiliation: | Ottawa-Carleton Institute for Research and Graduate Studies In Chemistry, Department of Chemistry, University of Ottawa, Ottawa, Ontario Canada KIN 9B4 |
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| Abstract: | Benzyl halides react with trialkylborates and carbon monoxide, in the presence of 1,5-hexadienerhodium chloride dimer, to give esters In excellent yields. The reaction is applicable to the synthesis of primary, secondary and even tertiary esters. |
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