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Preparation,structure and asymmetric diels-alder reactions of 10-arylsulfonylisobornyl acrylates
Authors:Wolfgang Oppolzer  Martha J. Kelly  Gérald Bernardinelli
Affiliation:Département de Chimie Organique, Université de Genève CH-1211 Genève, Switzerland
Abstract:
The crystalline chiral auxiliaries 4 and 5 were readily prepared from camphorsulfonic acid. Their acrylates underwent the diels-alder reactions 6 → 7 with modest asymmetric induction consistent with an X-ray study of 6a.
Keywords:
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