Intramolecular hydrogen abstraction. Iodosobenzene diacetate,an efficient and convenient reagent for alkoxy radical generation |
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| Authors: | José I. Concepción Cosme G. Francisco Rosendo Hernández José A. Salazar Ernesto Suárez |
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| Affiliation: | Instituto de Productos Naturales Orgánicos, C.S.I.C. Carretera La Esperanza 2, La Laguna, Tenerife, Spain |
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| Abstract: | ![]()
Photolysis of several hydroxy compounds in presence of iodosobenzene diacetate and iodine leads to alkoxy radical derivatives which undergo intramolecular hydrogen abstraction to produce cyclic ethers in good yield. |
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