The role of electronic factors in reagents in controlling thestereochemistry of arylsulfenyl chlorides addition |
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| Authors: | I.V. Bodrikov A.V. Borisov W.A. Smit A.I. Lutsenko |
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| Affiliation: | Gorky Polytechnical Institute, Minin str., 24, Gorky, U.S.S.R.;Zelinsky Institute of Organic Chemistry, Leninsky pr.47, Moscow, U.S.S.R. |
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| Abstract: | For a series of substituted arylsulfenyl chlorides the stereochemistry of AdE-reactions with a series of substituted Z- and E-β-deuterostyrenes has been elucidated. Non-stereospecific reaction was observed only for the pair 2,4-dinitrobenzenesulfenyl chloride-p-methoxystyrene; for all the other reactants the reaction proceeded in a strictly stereospecific manner. |
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