DMPM (3,4-dimethoxybenzyl) protecting group for hydroxy function more readily removable than MPM (P-methoxybenzyl) protecting group by DDQ oxidation |
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| Authors: | Yuji Oikawa Tatsuyoshi Tanaka Kiyoshi Horita Tadao Yoshioka Osamu Yonemitsu |
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| Institution: | Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo 060, Japan |
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| Abstract: | The DMPM (3,4-dimethoxybenzyl) protection for hydroxy function was deprotected more readily than the MPM (p-methoxybenzyl) protection by DDQ oxidation under neutral conditions, and applied to the synthesis of some synthons to macrolide and polyether antibiotics. |
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