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Asymmetric diels-alder reactions : facile preparation and structure of sulfonamido-isobornyl acrylates
Authors:Wolfgang Oppolzer  Christian Chapuis  Gérald Bernardinelli
Affiliation:Département de Chimie Organique, Université de Genève CH-1211 Genève, Switzerland
Abstract:
The crystalline chiral auxiliaries 2,3 and 4 were prepared from camphor-10-sulfonyl chlorides in 2 steps. Their readily accessible acrylates underwent efficient asymmetric diels-alder additions to cyclopentadiene, the topicity of which agrees with X-ray evidence.
Keywords:
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