Synthetic application of a substituent controlled claisen rearrangement. Preparation of advanced chiral intermediates for the synthesis of pseudomonic acids |
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| Authors: | Dennis P. Curran |
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| Affiliation: | Department of Chemistry University of Pittsburgh Pittsburgh, Pennsylvania 15260 U.S.A. |
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| Abstract: | ![]()
A substituent controlled Claisen rearrangement is employed as the key reaction for a facile construction of chiral intermediates for the synthesis of pseudomonic acids from diacetyl-L-arabinal. |
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