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New synthesis of 1-triacontanol
Authors:UT Bhalerao  SJagadishwar Rao  BD Tilak
Institution:Regional Research Laboratory, Hyderabad-500 007, India;Indian Institute of Education, 128/2, Karve Road, Kothrud, Pune, India.
Abstract:Succinic anhydride and behenic acid have been used to attach C4 and C22 carbon chains on to 2 and 5 positions of thiophene through two alternate acylation sequences. Raney nickel desulphurization to the 2,5-disubstituted thiophene yielded triacontanoic acid esters which on LAH reduction gave 1-triacontanol.
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