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Unsymmetrical selenides from selenocyanates and methyl grignard |
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| Authors: | Carol A. Loeschorn Charles J. Kelley Robert N. Hanson Michael A. Davis |
| Affiliation: | Department of Chemistry, Massachusetts College of Pharmacy and Allied Health Sciences, 179 Longwood Avenue, Boston, MA 02115 USA;Section of Medicinal Chemistry, College of Pharmacy and Allied Health Professions, Northeastern University, and Department of Radiology, Joint Program in Nuclear Medicine, Harvard Medical School, Boston, MA 02115 USA |
| Abstract: | The addition of methyl Grignard to diethyl acetamido(cyanoselenobenzyl)malonates 3 and 4 at ?78° followed by hydrolysis yields the 3-(4-and 3-methylselenophenyl)alanines 1 and 2. |
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