| 三桥联杯[6]酰腙衍生物和相关化合物的合成 |
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| 引用本文： | 许冰婷,杨发福,刘志强,柴先锋,郭红玉.三桥联杯[6]酰腙衍生物和相关化合物的合成[J].有机化学,2011,31(5). |
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| 作者姓名： | 许冰婷 杨发福 刘志强 柴先锋 郭红玉 |
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| 作者单位： | 1. 福建师范大学化学与材料学院,福州,350007
2. 福建师范大学化学与材料学院,福州,350007;福建师范大学福建省高分子材料重点实验室,福州,350007 |
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| 基金项目： | 国家自然科学基金，福建省自然科学基金，福建省高校杰出青年科研人才培育计划 |
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| 摘 要： | 以杯6]芳烃和杯6]-1,4-冠-4为起始原料,经过醚化引入酯基,接着用水合肼肼解得到杯6]酰肼衍生物2和6,然后再与水杨醛进行缩合反应,高产率合成了两例杯6]酰腙衍生物3和7.化合物6与2倍的二水杨醛乙二醚进行"1+2"缩合反应,得到了一例新型结构的杯6]-1,4-2,6-3,5-三桥联酰腙衍生物8,产率73%.新化合物2,3,6,7和8的结构经元素分析、红外光谱、质谱、核磁共振谱等证实.
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| 关 键 词： | 杯[6]芳烃 三桥联 酰腙 合成 |
Syntheses of Tri-bridging Calix[6]arene Hydrazone Derivative and Relative Compounds |
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| Xu Bingting,Yang Fafu,Liu Zhiqiang,Chai Xianfeng,Guo Hongyu.Syntheses of Tri-bridging Calix[6]arene Hydrazone Derivative and Relative Compounds[J].Chinese Journal of Organic Chemistry,2011,31(5). |
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| Authors: | Xu Bingting Yang Fafu Liu Zhiqiang Chai Xianfeng Guo Hongyu |
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| Institution: | Xu,Bingtinga Yang,Fafu*,a,b Liu,Zhiqianga Chai,Xianfenga Guo,Hongyua (a College of Chemistry and Materials,Fujian Normal University,Fuzhou 350007)(b Fujian Key Laboratory of Polymer Materials,Fuzhou 350007) |
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| Abstract: | Using calix6]arene and calix6]-1,4-crown-4 as starting materials,calix6]arene hydrazide de-rivatives 2 and 6 were prepared by introducing ester groups with etherification and following hydrazinolysis reaction.Condensating 2 and 6 with salicylaldehyde gave two calix6]arene hydrazone derivatives in high yields.By the 1+2 condensation of compound 6 with 2 equiv.ethylene glycol disalicylaldehyde ether,a novel calix6]-1,4-2,6-3,5-tri-bridging hydrazone derivative was synthesized in 73% yield.The structures ... |
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| Keywords: | calix[6]arene tri-bridging hydrazone synthesis |
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