|
|||||
|
|
Thiomorpholine-functionalized nanoporous mesopore as a sensing material for Cd2+ carbon paste electrode |
|
| Authors: | Mohammad Reza Ganjali Mehdi Asgari Farnoush Faridbod Parviz Norouzi Alireza Badiei Javad Gholami |
| Affiliation: | 1. Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran 2. Endocrinology and Metabolism Research Center, University of Tehran Medical Sciences, Tehran, Iran 3. School of Chemistry, College of Science, University of Tehran, Tehran, Iran |
| Abstract: | A new thiomorpholine-functionalized nanoporous mesopore Mobil Composition of Matter No. 41 (MCM-41), abbreviated as TMMCM-41, was synthesized and applied as a sensing material in construction of a cadmium carbon paste electrode. The electrode composition of 20.1%wt TMMCM-41, 54.0% graphite powder, 25.9% paraffin oil showed the stable potential response to Cd2+ ions with the Nernstian slope of 28.6 mV decade?1 (±1.8 mV decade?1) over a wide linear concentration range of 10?6 to 10?2?mol L?1 with a detection limit of 6?×?10?7 mol L?1. The electrode has fast response time and long-term stability (more than 4 months). The proposed electrode was used to determine the concentration of cadmium in tap water contaminated by this metal and cadmium electroplating waste water samples. |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ | |