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Synthesis of gold nanoparticle catalysts based on a new water-soluble ionic polymer
Authors:Biondi Ilaria  Laurenczy Gábor  Dyson Paul J
Affiliation:Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.
Abstract:A new water-soluble methyl-imidazolium-based ionic polymer was synthesized by ring-opening metathesis polymerization that was subsequently used to prepare aqueous gold nanoparticle solutions which were characterized by UV-vis spectroscopy and transmission electron microscopy (TEM). The aqueous gold nanoparticle solutions were employed as catalysts in the reduction of p-nitrophenol and in the hydrogenation of cinnamaldehyde and were found to exhibit excellent activity under mild conditions.
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