| 用氯离子电极同时测定阳离子表面活性剂的CMC及反离子缔合度 |
| |
| 引用本文： | 姚慧琴,高作宁.用氯离子电极同时测定阳离子表面活性剂的CMC及反离子缔合度[J].化学研究与应用,2004,16(4):543-544. |
| |
| 作者姓名： | 姚慧琴 高作宁 |
| |
| 作者单位： | 宁夏大学能源化工重点实验室,宁夏大学化学化工学院,宁夏,银川,750021;宁夏大学能源化工重点实验室,宁夏大学化学化工学院,宁夏,银川,750021 |
| |
| 基金项目： | 宁夏自然科学基金 (E10 0 1)，宁夏高等学校研究项目 ( 2 10 )，宁夏大学自然科学基金 ( 0 3 2 2 11)资助项目 |
| |
| 摘 要： | 临界胶束浓度(CMC)是研究表面活性剂的一个重要参数，胶束的反离子缔合度(K)是重要的特性参数。本文以阳离子表面活性剂十烷基三甲基氯化铵(DTMAC)、十二烷基三甲基氯化铵(DTAC)、十四烷基三甲基氯化铵(TTAC)、十六烷基三甲基氯化铵(CTAC)和十八烷基三甲基氯化铵(OTAC)水溶液体系为研究对象，用氯离子选择电极分别测定了其水溶液体系胶束的CMC和K。
|
| 关 键 词： | 氯离子选择性电极 阳离子表面活性剂 临界胶束浓度 反离子缔合度 |
| 文章编号： | 1004-1656(2004)04-0543-02 |
| 修稿时间： | 2003年10月13 |
Simultaneous determination of critical micelle concentration and counter-ion association degree of aqueous cationic surfactants solution system by chloride ion selective electrode |
| |
| YAO Hui-qin,GAO Zu-ning.Simultaneous determination of critical micelle concentration and counter-ion association degree of aqueous cationic surfactants solution system by chloride ion selective electrode[J].Chemical Research and Application,2004,16(4):543-544. |
| |
| Authors: | YAO Hui-qin GAO Zu-ning |
| |
| Institution: | YAO Hui-qin,GAO Zu-ning~* |
| |
| Abstract: | Both critical micelle concentration(CMC)and the counter-ion association degree (K) of aqueous cationic surfactants solutions (DTMAC,DTAC,TTAC,CTAC,OTAC)could be determined simultaneously by chloride ISE.The experimental results showed that the CMC were in agreement with the literature value.ISE was both simple and quick,and the results were accurate,reliable and satisfied.The reasons for the differences between the results obtained from both ISE and conductance methods were also discussed in detail in this paper. |
| |
| Keywords: | chloride ion selective electrode cationic surfactants critical micelle concentration counter-ion association degree |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
