| 配合物[Mn(phendione)(PDC)(H2O)2]·2H2O的合成与晶体结构 |
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| 引用本文： | 葛红光,孙妩娟,郭小华,赵蔡斌,许 琼. 配合物[Mn(phendione)(PDC)(H2O)2]·2H2O的合成与晶体结构[J]. 无机化学学报, 2007, 23(12): 2111-2114 |
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| 作者姓名： | 葛红光 孙妩娟 郭小华 赵蔡斌 许 琼 |
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| 作者单位： | 陕西理工学院化学与环境科学学院,汉中,723000 |
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| 基金项目： | 陕西省自然科学基金;陕西理工学院基金 |
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| 摘 要： | ![]()
The title compound [Mn(phendione)(PDC)(H2O)2]·2H2O (H2PDC=pyridine-2，6-dicarboxylic acid) has been prepared in aqueous solution and characterized by single X-ray diffraction structure determination， elemental analysis， IR spectroscopy， and thermal analyses. The compound crystallizes in Monoclinic system， space group C2/c， a=1.017 51(11) nm， b=1.483 25(11) nm， c=1.461 21(13) nm， β=109.86(10)°， V=2.074 1(3) nm3， Z=4， F(000)=1 028， μ=0.701 mm-1， Dc=1.609 g·cm-3， R1=0.028 9， wR2=0.078 8 [I>2σ(I)]. Crystal structure reveals that complex consists of one-dimensional chain framework bridged by hydrogen bonds that formed by uncoordinated water and oxygen atom of carboxyl group in PDC2-. Furthermore， the complexes form a three-dimensional super-molecular structure through hydrogen bonds. CCDC: 648570.
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| 关 键 词： | 1，10-菲咯啉-5，6-二酮 吡啶-2，6-二甲酸 锰配合物 晶体结构 |
| 文章编号： | 1001-4861(2007)12-2111-04 |
| 修稿时间： | 2007-06-18 |
Synthesis and Crystal Structure of the Complex [Mn(phendione)(PDC)(H2O)2]·2H2O |
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| GE Hong-Guang,SUN Wu-Juan,GUO Xiao-Hu,ZHAO Cai-Bin and XU Qiong. Synthesis and Crystal Structure of the Complex [Mn(phendione)(PDC)(H2O)2]·2H2O[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(12): 2111-2114 |
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| Authors: | GE Hong-Guang SUN Wu-Juan GUO Xiao-Hu ZHAO Cai-Bin XU Qiong |
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| Abstract: | ![]()
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| Keywords: | phendione H2PDC manganese complex crystal structure |
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