| Convenient Synthesis of Indene Derivatives via Intramolecular Friedel-Crafts Cyclization of Tetraaryl Substituted 1,3-Butadienes |
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| 引用本文： | 孙逊 泉铉治 胡昌奇 林国强. Convenient Synthesis of Indene Derivatives via Intramolecular Friedel-Crafts Cyclization of Tetraaryl Substituted 1,3-Butadienes[J]. 中国化学, 2006, 24(3): 430-434. DOI: 10.1002/cjoc.200690082 |
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| 作者姓名： | 孙逊 泉铉治 胡昌奇 林国强 |
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| 作者单位： | [1]Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China [2]Department of Chemistry of Natural Drugs, School of Pharmacy, Fudan University, Shanghai 200032, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No, 203900506） and the Shanghai Municipal Committee of Science and Technology （Nos, 05JC14057, 054319901）, |
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| 摘 要： |
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| 关 键 词： | 合成 茚衍生物 分子间环化作用 四芳基取代 1 3-丁二烯 Friedel-Crafts反应 双键转移 刘易斯酸 |
| 收稿时间： | 2005-08-25 |
| 修稿时间： | 2005-08-252005-12-19 |
Convenient Synthesis of Indene Derivatives via Intramolecular Friedel-Crafts Cyclization of Tetraaryl Substituted 1,3-Butadienes |
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| Sun Xun;Quan XuanZhi;Hu ChangJi;Lin GuoJiang. Convenient Synthesis of Indene Derivatives via Intramolecular Friedel-Crafts Cyclization of Tetraaryl Substituted 1,3-Butadienes[J]. Chinese Journal of Chemistry, 2006, 24(3): 430-434. DOI: 10.1002/cjoc.200690082 |
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| Authors: | Sun Xun Quan XuanZhi Hu ChangJi Lin GuoJiang |
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| Abstract: | A convenient and efficient method for the highly regioselecfive synthesis of indene derivatives 4 and 5 from tetraaryl substituted 1,3-butadienes 3 was described. The method involves an intramolecular Friedel-Crafts cyclization and a corresponding double-bond positional shift of isomers 4 and 5 in the presence of different Lewis acids under mild conditions with higher than 90% yields. |
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| Keywords: | multiaryl substituted indene derivative intramolecular cyclization Friedel-Crafts reaction doublebond positional shift Lewis acid |
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