Double molybdate Tl2Mg4(MoO4)3: Synthesis, structure, and properties |
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| Authors: | B. G. Bazarov R. F. Klevtsova Ts. T. Bazarova S. I. Arkhincheeva L. A. Glinskaya K. N. Fedorov Zh. G. Bazarova |
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| Affiliation: | (1) Baikal Institute of Nature Management, Siberian Division, Russian Academy of Sciences, ul. Sakhanova 8, Ulan-Ude, 670047, Buryat Republic, Russia;(2) Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia |
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| Abstract: | ![]()
Single crystals of molybdate Tl2Mg2(MoO4)3 are grown, and its crystal structure is refined in an X-ray diffraction experiment (an automated diffractometer, MoK α radiation, 914 F(hkl) reflections, R = 0.0459). The crystal are cubic with a = b = c = 10.700(1) Å, V = 1225.0(2) Å3, Z = 4, space group P213. The mixed 3D framework of the structure is built of MoO4 tetrahedra and two types of corner-sharing MgO6 octahedra. Two types of thallium atoms occupy large interstices. |
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