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Excess molar enthalpies of the ternary mixtures (1-hexene + tetrahydrofuran or 2-methyltetrahydrofuran + methyl tert-butyl ether) at the temperature 298.15 K
Authors:Christopher Q Lan
Institution:Department of Chemical Engineering, University of Ottawa, Ottawa, Ont., Canada K1N 6N5
Abstract:Microcalorimetric measurements of excess enthalpies at the temperature T = 298.15 K are reported for the binary mixture, (x1C6H12 + x2C4H8O) and the two ternary mixtures {x1C6H12 + x2(C4H8O or C5H10O) + x3(C5H12O)}. Smooth representations of the results are presented and used to construct constant excess molar enthalpy contours on Roozeboom diagrams. It is shown that good estimates of the ternary enthalpies can be obtained from the Liebermann and Fried model, using only the physical properties of the components and their binary mixtures.
Keywords:Excess enthalpy  Ternary mixture  1-Hexene  Tetrahydrofuran  2-Methyltetrahydrofuran  Methyl tert-butyl ether  Liebermann-Fried model
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