Insight into Oxide‐Bridged Heterobimetallic Al/Zr Olefin Polymerization Catalysts |
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| Authors: | Dr Cédric Boulho Dr Harmen S Zijlstra Alexander Hofmann Prof Dr Peter H M Budzelaar Prof Dr Sjoerd Harder |
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| Institution: | 1. Inorganic and Organometallic Chemistry, University of Erlangen-Nürnberg, Erlangen, Germany;2. Dutch Polymer Institute (DPI), P. O. Box 902, Eindhoven, Netherlands;3. Stratingh Institute, University of Groningen, Groningen, Netherlands;4. Department of Chemistry, University of Manitoba, Winnipeg, Canada |
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| Abstract: | Reaction of (TBBP)AlMe ? THF with Cp*2Zr(Me)OH] gave (TBBP)Al(THF)?O?Zr(Me)Cp*2] (TBBP=3,3’,5,5’‐tetra‐tBu‐2,2'‐biphenolato). Reaction of DIPPnacnacAl(Me)?O?Zr(Me)Cp2] with PhMe2NH]+B(C6F5)4]? gave a cationic Al/Zr complex that could be structurally characterized as its THF adduct (DIPPnacnac)Al(Me)?O?Zr(THF)Cp2]+B(C6F5)4]? (DIPPnacnac=HC(Me)C=N(2,6‐iPr2?C6H3)]2). The first complex polymerizes ethene in the presence of an alkylaluminum scavenger but in the absence of methylalumoxane (MAO). The adduct cation is inactive under these conditions. Theoretical calculations show very high energy barriers (ΔG=40–47 kcal mol?1) for ethene insertion with a bridged AlOZr catalyst. This is due to an unfavorable six‐membered‐ring transition state, in which the methyl group bridges the metal and ethene with an obtuse metal‐Me‐C angle that prevents synchronized bond‐breaking and making. A more‐likely pathway is dissociation of the Al‐O‐Zr complex into an aluminate and the active polymerization catalyst Cp*2ZrMe]+. |
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| Keywords: | alkene polymerization aluminum bimetallic catalysis synthetic methods zirconium |
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