Mechanism of the Reaction of 1,1-Dimethylhydrazine with Copper(II) and Palladium(II) Chloride Complexes Containing Poly-(N-2-Alcoxycarbonylethyl)-Ethyleneimine |
| |
| Authors: | I S Kalashnikova T L Lebedeva A A Grechnikov N A Plate B F Myasoedov |
| |
| Institution: | (1) Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 117912, Russia;(2) Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 117975, Russia |
| |
| Abstract: | The mechanism of the sorption of 1,1-dimethylhydrazine vapors with metal chloride complexes of poly-(N-2-R-oxycarbonylethyl)-ethyleneimines (R = –n-C4H9, –n-C10H21) was studied by Fourier transform IR spectroscopy (FTIR) and piezoelectric resonance. The structure of the products was determined. This allowed for the optimization of the chemical composition and structure of poly-(N-2-R-oxycarbonylethyl)-ethyleneimine-based complexes in their use as sensitive coatings of piezoelectric sensors for determining 1,1-dimethylhydrazine vapors in air. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
