Crystal and molecular structure of 1-aza-6′-(3′-oxo-5′, 5′-dimethyl-δ1′-pyrrolin-3′-yl)methylidene-2,2,7,7-tetramethyl-4-hydroxybicyclo-[2.2.21azaoctane |
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Authors: | V. E. Shklover Yu. T. Struchkov T. V. Medvedeva Yu. V. Korshak A. M. Shapiro |
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Affiliation: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | ![]() An x-ray structural study has shown that 6-(3 -oxo-5 ,5 -dimethyl- 1 -pyrrolin-3 -yl)methylidene-2,2,7, 7-tetramethyl-4-hydroxybicyclo[2.2.2]azaoctane is formed as a low-molecular-weight byproduct of the solid-phase polymerization of 1,4-bis(2,2,6,6-tetramethyl-4-hydroxy-4-piperidyl)butadiyne.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 585–587, March, 1990. |
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