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| 10-甲基吖啶盐与活泼金属在固相研磨条件下的新颖反应研究 | |
| 引用本文： | 许华建,徐小岚,冯乙巳.10-甲基吖啶盐与活泼金属在固相研磨条件下的新颖反应研究[J].有机化学,2009,29(2):289-291. |
| 作者姓名： | 许华建 徐小岚 冯乙巳 |
| 作者单位： | 1. 合肥工业大学化学工程学院,合肥,230009 2. 安徽医科大学化学教研室,合肥,230032 |
| 基金项目： | 国家自然科学基金，高等学校博上学科点专项科研基金，合肥工业大学博上专项科研基金 |
| 摘 要： | 在固相研磨条件下, 10-甲基吖啶碘盐与碱金属Li, Na和K反应生成9,10-二氢-10-甲基吖啶(AcrH2)和10-甲基-9-吖啶酮(Acr＝O), 产率比较高. 这些反应是通过金属将电子转移给10-甲基吖啶碘盐而得以发生的. |
| 关 键 词： | 辅酶NADH模型物 固相 研磨 电子转移 |
| 收稿时间： | 2008-6-6 |
| 修稿时间： | 2008-8-5 |
A Novel Reaction of 10-Methylacridinium with Reactive Metals under Grinding |
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| Xu Huajian,Xu Xiaolan,Feng Yisi.A Novel Reaction of 10-Methylacridinium with Reactive Metals under Grinding[J].Chinese Journal of Organic Chemistry,2009,29(2):289-291. | |
| Authors: | Xu Huajian Xu Xiaolan Feng Yisi |
| Institution: | (a School of Chemical Engineering, Hefei University of Technology, Hefei 230009) (b Department of Chemistry, Anhui Medical University, Hefei 230032) |
| Abstract: | Under grinding, 10-methylacridinium iodide was reacted with alkaline metal Li, Na, or K to give 9,10-dihydro-10-methylacridine (AcrH2), and 9,10-dihydro-10-methyl-9-acridone (Acr＝O) in excellent yields, which can be understood in terms of an initial electron transfer from metal to 10-methylacridinium iodide. |
| Keywords: | coenzyme NADH model solid phase grinding electron transfer |
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