Complexes of a [2]rotaxane ligand with terminal terpyridine groups |
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| Authors: | Mercer Darren J Loeb Stephen J |
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| Institution: | Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, CanadaN9B 3P4. |
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| Abstract: | Permanently interlocked 2]rotaxane ligands can be created by capping a pyridine terminated 2]pseudorotaxane with terpyridine containing stoppers. The robust nature of the resulting 2]rotaxane ligand allows coordination to inert metals such as Ru(II) not possible under standard self-assembly conditions. |
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