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Enhancive Synthesis of ‐lβ, 11‐Diol‐4‐en‐eudesmol
Authors:Jin‐Chun Chen  Guo‐Jun Zheng  Chen Zhang  Li‐Jing Fang  Yu‐Lin Li
Abstract:
An enhancive synthesis of ?1β, 11‐diol‐4‐en‐eudesmol, starting from 2‐chloroacrylonitrile, is described. The effect of temperature on the Diels‐Alder reaction of 2‐chloroacrylonitrile with 2‐methylfuran and the condition of cationic cyclization of diene were discussed in detail.
Keywords:Diels‐Alder reaction  cationic cyclization  eudesmane  sesquiterpenoids
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