Improved charge transport in dye-sensitized solar cells employing viscous non-volatile electrolytes |
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Authors: | Soon Hyung Kang Moon-Sung Kang Sang-Hyun Choi Jae-Yup Kim Hyun-Sik Kim Taeghwan Hyeon Yung-Eun Sung |
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Affiliation: | aSchool of Chemical and Biological Engineering and Interdisciplinary Program in Nano Science and Technology, Seoul National University, Seoul 151-742, Republic of Korea;bSamsung Advanced Institute of Technology, Energy and Environmental Laboratory, Gyeonggi-Do 446-712, Republic of Korea |
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Abstract: | Dye-sensitized solar cells (DSSCs) employing a viscous non-volatile electrolyte were prepared by utilizing anatase TiO2 nanorods (synthesized via oriented attachment) as a photoanode material. One promising way to enhance the photovoltaic performance of DSSCs employing viscous electrolytes is to increase ion conductivity by increasing the salt concentration. This is accompanied by an acceleration of the charge recombination reaction and the limiting of the overall conversion efficiency. The results showed that a TiO2 nanorod electrode enables more favorable electron transport than a conventional nanoparticle-based electrode due to the improved electron diffusion length and the large intrinsic surface area. |
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Keywords: | TiO2 nanorod Dye-sensitized solar cell Non-volatile electrolyte Ion conductivity Electron diffusion length |
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